N-metalated imines by reaction of 1,1-diethoxybut-2-ene with aromatic nitriles, as useful intermediates for the synthesis of substituted pyrimidines and cyclopentenones.

نویسندگان

  • Marco Blangetti
  • Annamaria Deagostino
  • Cristina Prandi
  • Chiara Zavattaro
  • Paolo Venturello
چکیده

A new approach to the synthesis of pyrimidines and cyclopentenones is described. The method exploits the reactivity of alpha,beta-unsaturated acetals with aromatic nitriles in the presence of the Schlosser's superbase LIC-KOR.

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عنوان ژورنال:
  • Chemical communications

دوره 14  شماره 

صفحات  -

تاریخ انتشار 2008